Desvenlafaxinium chloranilate ethyl acetate solvate
نویسندگان
چکیده
In the cation of the title compound, C16H26NO2 (+)·C6HCl2O4 (-)·C4H8O2, the 1-hy-droxy-cyclo-hexyl ring adopts a slightly distorted chair conformation. The dihedral angle between the mean planes of the 1-hy-droxy-cyclo-hexyl and 4-hy-droxy-phenyl rings is 84.0 (8)°. In the anion, the hydroxyl H atom is twisted slightly out of the ring plane with a C-C-O-H torsion angle of -171.9°. Disorder was modeled for the methyl group of the acetate group in the solvate with an occupancy ratio of 0.583 (15): 0.417 (15). In the crystal, O-H⋯O hydrogen bonds are observed between cations and between cations and anions, while bifuricated N-H⋯(O,O) cation-anion hydrogen bonds are also present, forming chains along [010] and [100]. In addition weak cation-anion and cation-solvate C-H⋯O inter-actions occur.
منابع مشابه
cis-Dichloridobis{[4-(dimethylamino)phenyl]diphenylphosphane-κP}platinum(II) ethyl acetate monosolvate
The title compound, [PtCl(2)(C(20)H(20)P)(2)]·C(4)H(8)O(2), crystallizes with the Pt atom in a distorted cis-square-planar geometry. The Pt-P bond lengths are 2.2490 (19) and 2.253 (2) Å, and the Pt-Cl bond lengths are 2.344 (2) and 2.3475 (18) Å. Some weak C-H⋯Cl and C-H⋯O inter-actions involving the solvate mol-ecule were observed.
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013